The Ce3+ Metal Ion Adsorbent Based on Calcium Alginate Loaded Fe3O4 (Ca-Alg/Fe3O4)
DOI:
https://doi.org/10.59890/ijarss.v1i4.1094Keywords:
Adsorption, Alginate, Fe3O4, Cerium, Rare Earth ElementsAbstract
Rare earth metal frequently utilized in technological advancements is cerium. The high utilization of cerium correlates with the depletion of primary REEs reserves and the accumulation of secondary materials that can enter aquatic environments. Recycling and recovery of REEs through methods such as solvent extraction, filtration, and adsorption are commonly employed. Adsorption is chosen due to the abundance of adsorbent materials in nature, simple fabrication, efficiency, and cost-effectiveness. Calcium alginate biosorbent loaded with magnetite (Ca-Alg/Fe3O4) has been used to adsorb (Ce3+)aq, with optimal conditions achieved at Ca-alginate:Fe3O4 ratio of 2:1 (w/w), 0.075 g, pH 4, a contact time of 210 minutes, and 250 ppm, [Ce3+]0. The adsorption process follows the Langmuir isotherm model with qmax at 50.505 mg/g. Hence, the Ca-Alg/Fe3O4 biosorbent shows potential in adsorbing (Ce3+)aq.
References
Asip, f., & mardhiah, r. (2008). Uji efektifitas cangkang telur dalam mengadsorbsi ion fe dengan proses batch (vol. 15, issue 2).
Atkins. P. W, . (1997). Kimia fisika 2. Erlangga.
Chen, q. (2010). Study on the adsorption of lanthanum(iii) from aqueous solution by bamboo charcoal. Journal of rare earths, 28, 125–131. Https://doi.org/10.1016/s1002-0721(10)60272-4
Dada, a. O., olalekan, a. P., olatunya, a. M., & dada, o. (2012). Langmuir, freundlich, temkin and dubinin-radushkevich isotherms studies of equilibrium sorption of zn 2+ unto phosphoric acid modified rice husk. In iosr journal of applied chemistry (iosr-jac (vol. 3, issue 1). Www.iosrjournals.org
Goonan, t. G. (2011). Rare earth elements-end use and recyclability: u.s. geological survey scientific investigations report 2011–5094.
Kim, j. (1997). Studies on complexation and solvent extraction of lanthanides in the presence of diaza-18-crown-6-di-isopropionic acid. Talanta, 45(2), 437–444. Https://doi.org/10.1016/s0039-9140(97)00151-3
Lim, s.-f., zheng, y.-m., zou, s.-w., & chen, j. P. (2008). Characterization of copper adsorption onto an alginate encapsulated magnetic sorbent by a combined ft-ir, xps, and mathematical modeling study. Environmental science & technology, 42(7), 2551–2556. Https://doi.org/10.1021/es7021889
Liu, z. L., liu, y. J., yao, k. L., ding, z. H., tao, j., & wang, x. (2002). Synthesis and magnetic properties of fe3o4 nanoparticles. Journal of materials synthesis and processing, 10(2), 83–87. Https://doi.org/10.1023/a:1021231527095
Mahmoud hamdy el ghandoor, h., zidan, h. M., khalil, m., m ismail, m. I., ghandoor, he., & khalil, m. M. (2012). Synthesis and some physical properties of magnetite (fe 3 o 4 ) nanoparticles. In int. J. Electrochem. Sci (vol. 7). Www.electrochemsci.org
Mortimer, r. G. (2008). Physical chemistry third edition. Elsevier akademic press.
Murthy, z. V. P., & choudhary, a. (2011). Separation of cerium from feed solution by nanofiltration. Desalination, 279(1–3), 428–432. Https://doi.org/10.1016/j.desal.2011.06.014
Panneerselvam, p., morad, n., & tan, k. A. (2011). Magnetic nanoparticle (fe3o4) impregnated onto tea waste for the removal of nickel(ii) from aqueous solution. Journal of hazardous materials, 186(1), 160–168. Https://doi.org/10.1016/j.jhazmat.2010.10.102
Rusnadi, r., buchari, b., amran, m. B., & wahyuningrum, d. (2012). Cerium adsorption using 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone (hpmbp) loaded calcium alginate beads. Journal of engineering research and applications (ijera), 2, 496–862.
S. J. Suprapto. (2009). Tinjauan tentang unsur tanah jarang. Bidang program dan kerja sama - pusat sumber daya geologi.
S. Sound, m. Of, & o. U. R. Mineral. (2002). Rare earth elements — critical resources for high technology.
Sert, ş., kütahyali, c., inan, s., talip, z., çetinkaya, b., & eral, m. (2008). Biosorption of lanthanum and cerium from aqueous solutions by platanus orientalis leaf powder. Hydrometallurgy, 90(1), 13–18. Https://doi.org/10.1016/j.hydromet.2007.09.006
Thanh, t. T. T., quach, t. T. M., tran, v. T. T., nguyen, t. V., suzuki, s., kitamura, s., & yuguchi, y. (2021). Structural characteristics and biological activity of different alginate blocks extracted from brown seaweed turbinaria ornata. Journal of carbohydrate chemistry, 40(1–3), 97–114. Https://doi.org/10.1080/07328303.2021.1928155
V. Gopalakannan, & n. Viswanathan. (2015). Synthesis of magnetic alginate hybrid beads for efficient chromium (vi) removal. International journal biology macromolecules, 72, 862–867.
Wu, d., niu, c., li, d., & bai, y. (2004). Solvent extraction of scandium(iii), yttrium(iii), lanthanum(iii) and gadolinium(iii) using cyanex 302 in heptane from hydrochloric acid solutions. Journal of alloys and compounds, 374(1–2), 442–446. Https://doi.org/10.1016/j.jallcom.2003.11.058
Wu, d., zhao, j., zhang, l., wu, q., & yang, y. (2010). Lanthanum adsorption using iron oxide loaded calcium alginate beads. Hydrometallurgy, 101(1–2), 76–83. Https://doi.org/10.1016/j.hydromet.2009.12.002
Xiong, c., meng, y., yao, c., & shen, c. (2009). Adsorption of erbium(iii) on d113-iii resin from aqueous solutions: batch and column studies. Journal of rare earths, 27(6), 923–931. Https://doi.org/10.1016/s1002-0721(08)60364-6
Yao, c. (2010). Adsorption and desorption properties of d151 resin for ce(iii). Journal of rare earths, 28, 183–188. Https://doi.org/10.1016/s1002-0721(10)60324-9
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2023 Hulqi Mila Haili, Rusnadi; Silmi Nur'asni Yulianti

This work is licensed under a Creative Commons Attribution 4.0 International License.



